Aherne, Julian

A key knowledge gap in aeolian transport research concerns the adjustment of saltation processes to the extreme conditions found within high-latitude regions. A series of wind tunnel experiments were carried out under full climate control and over a wide range in humidity. Particle entrainment and transport within shearing flows of varied wind speed were monitored over beds of varied temperature, and ice content to determine their affect on 1) particle trajectory, 2) saltation cloud height, 3) particle velocity, 4) surface erosivity, 5) mass transport rate and 6) vertical dust flux. Particles were found to have higher velocities over cold beds than dry beds. With a 3% increase in bed moisture content, a significant increase in particle velocity was measured. Fewer particles are ejected from a bed with moisture than a dry bed. The mass transport rate was measured to be 23% higher at -10 degrees Celsius compared to 30 degrees Celsius.

Author Keywords: Aeolian processes

Dissolved inorganic carbon in drainage waters is a direct measurement of carbon dioxide (CO2) removal from enhanced rock weathering (ERW) in soils. In this study, square metre scale field experiments (2021–2023) were conducted in Peterborough Ontario, Canada, each amended with kimberlite residues from Gahcho Kué Diamond Mine (Northwest Territories, Canada) or olivine powder at high application rates (100–400 t/ha). Porewater chemistry data, coupled with a water budget analysis derived from precipitation and soil moisture data, were used to quantify solubility trapping by amendment weathering revealing maximum rates of 0.04 t CO2/ha over 2 yr for olivine and 0.9 t CO2/ha over 3 yr for kimberlite. This research presents kimberlite mine wastes as an ERW feedstock alternative to basalt as projects scale-up and require more rock. Additionally, high dosage monitoring plots ensure detection of a CO2 removal signal in open systems and should be considered for large scale projects.

Author Keywords: CO2 removal, Enhanced rock weathering, Field experiment, Kimberlite, Mine wastes, Olivine

This thesis determined the temporal dynamics of microplastics in the biosolid and final effluent of a WWTP for one year (October 2020–September 2021). The WWTP exported 354.1 ± 24.7 billion microplastic particles, or 296.7 ± 39.4 kg of microplastics; of this, 85.7% of counts and 86.6% of mass was exported via biosolids. As such, microplastic loads in biosolids need to be reduced before they are land applied. This thesis further examined the ability of settling treatments to liberate microplastics from biosolids under the effect of four variables (harvest method, stirring, settling time, and biosolid type). Across all treatments, average microplastic removal was 9.01 ± 5.82% in terms of count, and 6.91 ± 4.98% in terms of mass. Overall, this thesis contributed to our understanding of annual microplastic burden in a WWTP and set the foundation for the development of settling-based biosolids treatments to reduce microplastic emissions to the environment.

Author Keywords: Biosolid, Count Concentration, Final Effluent, Mass Concentration, Polymer, Treatment

Microplastics are intricate plastic particles (<5 mm in length) with complex chemical mixtures that are pervasive globally. Nonetheless, our understanding of microplastic contamination in the Canadian Arctic is limited. Therefore, this thesis aimed to investigate the concentration and characteristics of microplastics in and surrounding the community of Iqaluit, Nunavut. Our findings suggest Iqaluit is a local source of microplastics in the Arctic based on their concentration in road dust (2.83 ± 3.72 µg/g). Microplastic concentrations were comparable to those in metropolitan areas and given their abundance in parking lots it is suggested that these are temporary reservoirs for microplastics and tire wear particles. Further, lakes predominately upwind of Iqaluit had a greater concentration of microplastics (134 ± 204 µg/L) than lakes downwind (30.8 ± 55.5 µg/L). These findings underscore the importance of assessing both local-scale and long-range sources when examining microplastic contamination in the Arctic.

Author Keywords: Atmospheric microplastics, Biomonitoring, Canadian Arctic, Fourier-Transform Infrared Spectroscopy (FTIR), Plastic pollution

In this study, twenty lake catchments surrounding Iqaluit, Baffin Island, were assessed for trace element concentrations (Al, As, Ba, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Sb, Se, THg, V, Zn) in lake water, catchment soil, lake sediment, and moss (Hylocomium splendens). Additionally, the sources of each trace element were determined through the positive matrix factorization (PMF) model and enrichment factors (only in moss). Geogenic trace elements had the highest median concentrations (Fe>Al>Mn) throughout the study media and across the study catchments. Anthropogenic trace elements had the lowest median concentrations (Pb>As>Cd>THg) across the lake catchments, which were generally several orders of magnitude lower compared to geogenic elements. The PMF model identified trace elements associated with geogenic or anthropogenic sources, i.e., THg (47%), Cd (40%), Zn (34%), and Al (27%) were identified as originating from industrial emission sources deposited onto lakes because they accounted for a large proportion within the model.

Author Keywords: Arctic lake catchments, Biomonitoring, Enrichment factors, Positive matrix factorization model, Trace elements, Water chemistry

This study examines the atmospheric (synoptic) controls on snowmelt and snow-free season carbon dioxide (CO2) fluxes at Daring Lake, Northwest Territories. Atmospheric circulation patterns were derived from 500 hPa geopotential height and classified using the self-organizing maps artificial neural network. Snowmelt timing was not found to be influenced by atmospheric circulation patterns or large-scale teleconnection indices, but a shift from meridional to zonal atmospheric circulation marked the transition from pre-melt to melt period. Multiple linear regression identified heating degree days and incoming solar radiation as the most important meteorological predictors of melt length; however, the model would have benefitted from additional variables. Analysis of CO2 (net ecosystem exchange, NEE) during the snow-free season highlighted a strong correlation between NEE and temperature anomalies. Like the snowmelt period, no atmospheric circulation patterns were found to significantly influence NEE; however, these findings prompt further questions regarding snowmelt and CO2 fluxes in the Canadian low Arctic.

Author Keywords: atmospheric circulation, carbon fluxes, net ecosystem exchange, self-organizing maps, snowmelt, synoptic patterns

Chromophoric dissolved organic matter (CDOM), a chemically diverse family of organic compounds defined by their ability to absorb ultraviolet and visible light, is a critical constituent of numerous environmental systems, including freshwater lakes. Industrial operations in the Athabasca Oil Sands Region (AOSR, Alberta, Canada) are major sources of acidic inorganic gases and organic contaminants to the atmosphere, the subsequent deposition of which posed the potential to alter the composition of natural CDOM within surrounding lake surface-waters. The objective of this thesis was to determine if OS sources measurably impacted CDOM quality within 50 regionally monitored acid sensitive lakes by means of a) altered acid-base chemical processes or b) industrial atmospheric CDOM inputs. Ultraviolet-visible light spectroscopy and excitation emission matrix (EEM) fluorescence spectroscopy were applied to characterize CDOM within regional lake surface-waters to identify the primary sources (e.g., natural, anthropogenic) and process (e.g., acid-base chemistry) influencing chromophoric organic matter quality. These spectroscopic techniques were further used to evaluate industrial CDOM within atmospheric aerosols and deposition to assist with the identification of industrial CDOM within lake waters. Spectroscopic analysis of regional lake surface-water found weak associations between CDOM and acid-base variables, suggesting that acid inputs from OS sources would have limited influence over surface-water chromophoric organic matter. A distinct fluorescent component (i.e., fluorophore) measured within the lake samples (C3) displayed decreasing emission intensity as a function of distance from OS sources and positive correlations with surface-water polycyclic aromatic compounds, implying industrial influence. Spectral similarity between C3 and industrial fluorophores observed from regional aerosol and atmospheric deposition samples further confirmed the lake fluorophore was linked to OS sources. This research suggests that EEM fluorescence spectroscopy could be used as a cost-effective technique to detect industrial pollution within lake surface-waters throughout the AOSR.

Author Keywords: atmospheric brown carbon, atmospheric deposition, atmospheric pollution, dissolved organic matter, fluorescence spectroscopy, lake chemistry

Mining and smelting degraded landscapes are characterised by heavily eroded soils that are acidic, contaminated with toxic metals, and depleted of essential nutrients. Regreening degraded landscapes has been proposed to support global carbon (C) mitigation measures and protect biodiversity. One of the world's largest regreening programs in the City of Greater Sudbury, Canada has been ongoing since 1978 and involves liming and fertilizing selected areas followed by planting primarily jack pine (Pinus banksiana Lamb.) and red pine (Pinus resinosa Ait.) trees. The main objective of this thesis was to improve our understanding of biogeochemistry in the City of Greater Sudbury regreened forests, and to determine how nutrient pools and cycling change as stands age. I established a chronosequence of forested sites between 15–40 years-old and to account for the effects of erosion, each site was categorized as "stable" (<10% bedrock cover) or "eroded" (>30% bedrock cover). Individual tree growth and nutrient accumulation in aboveground biomass (AGB) did not differ between stable and eroded sites and were comparable to rates reported from pine plantations in similar ecozones. Aboveground nitrogen (N) pools were six times larger than N applied in fertilizer, suggesting N limitation is most likely not a concern. Rates of C cycling were generally similar to those measured at unimpacted jack and red pine plantations. The exception being a decrease in mineral soil and aggregate C concentrations. However, at the ecosystem-scale the loss of soil C is trivial in comparison to increases in AGB C pools, leading to an overall increase in total ecosystem C following regreening (550,547 Mg in aboveground C across the 19,649 ha regreening landscape). Litter decomposition rates were higher at the regreening sites using a site-specific litter compared to a general common litter, indicating a home-field advantage for local decomposers. Soil temperature varied at the regreening sites and higher soil temperatures were related to higher rates of soil respiration. The regreening sites are rich in calcium (Ca) and magnesium (Mg); and while soils were generally poor in phosphorous (P) and potassium (K), foliar concentrations of P and K were comparable to those of "healthy" red pines. Overall, the regreening program appears to have increased tree growth and produced jack and red pine plantations that are biogeochemically similar to conifer plantations unimpacted by over a century of mining and smelting impacts.

Author Keywords: biogeochemistry, degraded landscape, forests, nutrient cycling, regreening, soil carbon

A key knowledge gap in aeolian transport research concerns the adjustment of saltation processes to the extreme conditions found within high-latitude regions. A series of wind tunnel experiments were carried out under full climate control and over a wide range in humidity. Particle entrainment and transport within shearing flows of varied wind speed were monitored over beds of varied temperature, and ice content to determine their affect on 1) particle trajectory, 2) saltation cloud height, 3) particle velocity, 4) surface erosivity, 5) mass transport rate and 6) vertical dust flux. Particles were found to have higher velocities over cold beds than dry beds. With a 3% increase in bed moisture content, a significant increase in particle velocity was measured. Fewer particles are ejected from a bed with moisture than a dry bed. The mass transport rate was measured to be 23% higher at -10 degrees Celsius compared to 30 degrees Celsius.

Author Keywords: Aeolian processes

In this study, twenty lake catchments surrounding Iqaluit, Baffin Island, were assessed for trace element concentrations (Al, As, Ba, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Sb, Se, THg, V, Zn) in lake water, catchment soil, lake sediment, and moss (Hylocomium splendens). Additionally, the sources of each trace element were determined through the positive matrix factorization (PMF) model and enrichment factors (only in moss). Geogenic trace elements had the highest median concentrations (Fe>Al>Mn) throughout the study media and across the study catchments. Anthropogenic trace elements had the lowest median concentrations (Pb>As>Cd>THg) across the lake catchments, which were generally several orders of magnitude lower compared to geogenic elements. The PMF model identified trace elements associated with geogenic or anthropogenic sources, i.e., THg (47%), Cd (40%), Zn (34%), and Al (27%) were identified as originating from industrial emission sources deposited onto lakes because they accounted for a large proportion within the model.

Author Keywords: Arctic lake catchments, Biomonitoring, Enrichment factors, Positive matrix factorization model, Trace elements, Water chemistry