Abstract: <p>This work presents a new online method using gas chromatography coupled to the multicollector-inductively coupled plasma-mass spectrometer for methylmercury (MMHg) isotope ratio measurement. An extraction method using distillation was developed that effectively extracted MMHg from up to 5 grams of sediment, imparting no isotope fractionation on MMHg during extraction. Isotope ratios from… more
Abstract: <p>A meta-analysis revealed that while there is often a greater degree of contamination of soils and sediments with metals, contamination by mercury (Hg) is a large concern owing to its toxicity at low concentrations. The case study in Guyana characterized Hg and concentrations of other metals (As, Cd, Co, Cu, Mn, Ni, Pb, and Zn) in soil and sediment within gold mined areas. Metal… more