English

Arctic terrestrial ecosystems have experienced substantial structural and compositional changes in response to warming climate in recent decades, especially the expansion of shrub species in Arctic tundra. Climatic and vegetation changes could feedback to the global climate by changing the carbon balance of Arctic tundra. The objective of this thesis was to investigate the influence of increased shrub coverage on carbon exchange processes between atmosphere and the Arctic tundra ecosystem. In this study a space-for-time substitution was used, referred to as a shrub expansion "chronosequence", with three sites along a natural gradient of deciduous shrub coverage in the Canadian low Arctic. Leaf-level photosynthetic capacity (Amax) of dominating birch shrub Betula glandulosa (Michx.) was significantly higher (P<0.05) at the site where shrubs were more abundant and taller than at the other sites. For all sites, mean Amax in 2014 was significantly lower than in 2013, in part potentially due to differences in precipitation distribution. Bulk soil respiration (RS) rate was significantly higher (P<0.05) at the site with more shrubs compared with the other sites. The differences in RS across sites appeared to be driven by differences in soil physiochemical properties, such as soil nitrogen and soil bulk density rather than soil microclimate factors (e.g. soil temperature, moisture). The three sites were either annual CO2 sources (NEP<0) to the atmosphere or CO2 neutral, with strongest annual CO2 sources (-44.1±7.0 g C m-2) at the site with most shrubs. Overall this study suggests that shrubs tundra carbon balance will change with shrub expansion and that shrub ecosystems in the Arctic currently act as annual carbon sources or neutral to the atmospheric CO2 and further shrub expansion might strengthen the CO2 emissions, causing a positive feedback to the warming climate.

Author Keywords: arctic tundra, carbon exchange, climate change, photosynthetic capacity, shrub expansion, soil respiration

This thesis provides an analysis of the Carnegie Commission's report on the causes and consequences of the Balkan Wars (1912-1913). Shortly after the closing of hostilities, the Carnegie Endowment for International Peace appointed an international Commission of Inquiry to collect evidence of atrocities from the sites of war. The thesis analyzes the arguments expressed in the Commission's report as an example of European and American attitudes towards the Balkans. The concept of Balkanism provides a theoretical framework according to which the Commissioners' views are contextualized within the existing stereotypes of the region. Based on the correspondence available in the archives of the Carnegie Endowment for International Peace, the memoirs and biographies of the various members of the Commission, and the information published in periodicals, this work also examines the justifications for the appointment of the Commission, the circumstances related to the investigation of atrocities and the reaction of Balkan governments to the report.

Keywords: Carnegie Report, Carnegie Commission, Carnegie Endowment for International Peace, Balkan Wars, Balkanism.

Author Keywords: Balkanism, Balkans, Balkan Wars, Carnegie Commission, Carnegie Endowment, Carnegie Report

During the 1970s, ideological divisions caused by divergent interpretations of the American failure in Vietnam permeated the world of foreign policymaking. This led to a concern among the architects of the Reagan administration that foreign policymaking had become incoherent. They attempted to mitigate the effects of this disharmony by re-establishing a workable degree of ideological conformity within the foreign policy bureaucracy. This thesis focuses on the strategy used to improve ideological conformity and its effect on the foreign policy bureaucracy's ability to produce well informed policy. Using case studies of two of Reagan's ambassadors to Central America, it argues that Reagan's strategy created a foreign policy bureaucracy that manufactured uninformed policy. The influence granted to officials who based their recommendations on regional expertise was severely curtailed. This shift produced a subsequent change in diplomatic practice, as foreign service officers adapted to the demand for allegiance to the president's agenda.

Author Keywords: American Foreign Policy, Central America, Ronald Reagan

Environmental variation can affect consumer trait expression and alter ecological and evolutionary dynamics in natural populations. However, although dietary nutrient content can vary by an order of magnitude in natural ecosystems, intra-specific differences in consumer responses to food quality have not been thoroughly investigated. Therefore, the purpose of my dissertation was to examine the influence of dietary nutrition and other environmental factors on consumer phenotypic variation using the freshwater cladoceran Daphnia. I conducted a series of complementary laboratory and field studies where I examined the effects of dietary phosphorus (P) content and additional biological/environmental variables (multi-elemental limitation, genetic variation, and temperature) on daphnid life-history, biochemistry, body elemental composition, and population growth. In general, phenotypic expression within a species varied significantly in response to all experimental variables, but the relative influence of each was highly context dependent. In my first chapter, I found that dietary P content and environmental calcium (Ca) concentrations both altered Daphnia body Ca:P ratios and growth rates of individuals and affected intrinsic rates of increase at the population level. However, food quality appeared to have a much larger effect on trait expression, and body Ca:P ratios were highly sensitive to other forms of dietary nutrient limitation. Next, I documented significant quantitative genetic variation and phenotypic plasticity in daphnid P content, growth, and P use efficiency of field collected animals grown across dietary P gradients. Trait expression was also influenced by genotype X diet interactions suggesting that consumer responses to dietary nutrient limitation can be heritable and may be adaptive in different nutrient environments. Finally, I found that temperature appeared to override food quality effects and decouple P metabolism in natural Daphnia populations, but total biomass production was affected by both dietary P content and temperature, depending on the nutrient content of the lake. Overall, my dissertation shows that consumer responses to nutrient limitation can vary significantly within a species and that changes in trait expression may be modified by other environmental variables. These results should be incorporated into existing stoichiometric models and used to investigate the eco-evolutionary consequences of consumer phenotypic variation in response to nutritional stress.

Author Keywords: ecological stoichiometry, evolution, life-history, nutrient limitation, nutrient metabolism, zooplankton

The flavohemoglobin in Giardia intestinalis (gFlHb) is the only known protozoan member of a protein class typically associated with detoxifying nitric oxide (by oxidation to nitrate) in bacteria and yeast. Mutants of the B10 tyrosine (Y30F) and E11 leucine (L58A), conserved residues thought to influence ligand binding, were expressed and studied using Resonance Raman (RR) spectroscopy. In the wild type protein, RR conducted using a carbon monoxide probe detects two distinct Fe-CO stretches associated with two different active site configurations. In the open configuration, CO does not interact with any polar side chains, while in the closed configuration, CO strongly interacts with one or more distal residues. Analysis of the Y30F mutant provided direct evidence of this tyrosine's role in ligand stabilization, as it had only a single Fe-CO stretching mode. This stretching mode was higher in energy than the open conformer of the wild type, indicating a residual hydrogen bonding interaction, likely provided by the E7 glutamine (Q54). In contrast the L58A mutant had no effect on the configurational nature of the enzyme. This was unexpected, as the side chain of L58 sits atop the heme and is thought to regulate the access of distal residues to the heme-bound ligand. The similar spectroscopic properties of wild type and L58A suggest that any such regulation would involve rapid conformational dynamics within the heme pocket.

Author Keywords: B10 Tyrosine, Catalytic Globin, E11 Leucine, Flavohemoglobin, gFlHb, Giardia intestinalis

This dissertation focuses on the English-language anarchist periodical press in the United States in the 1890s and early 1900s. Each of the three chapters of this dissertation examines one anarchist paper and its coverage of a specific issue. The first chapter focuses on Prison Blossoms, which was started by Alexander Berkman, Carl Nold, and Henry Bauer and written and circulated in the Western Penitentiary of Pennsylvania, and its engagement with Alexander Berkman's attempt to assassinate Henry Clay Frick. The second chapter examines Free Society, a weekly edited primarily by Abraham Isaak, and its contributors' writings on the assassination of President William McKinley by self-described anarchist Leon Czolgosz. Finally, the third chapter focuses on The Demonstrator, specifically its first volume which was edited by James F. Morton Jr. from the intentional community of Home, Washington, and the paper's work in supporting John

Turner, the first anarchist targeted for deportation under the Immigration Act of 1903. Drawing upon critical discourse analysis, this dissertation incorporates examination of the context in which these papers were written (particularly the immediate concerns to which the papers' authors responded), the form and generic conventions of the anarchist press, including the approaches of the papers' respective editors, and the

arguments advanced by their authors. It pays particular attention to the intertextuality of the anarchist press -- the ways in which those writing in anarchist papers addressed one another both within and across periodicals, generating anarchist thought through conversation and debate and enacting their anarchist ideals in the practice of publishing.

This dissertation demonstrates that the anarchist periodical press, an element of anarchist history that has received little attention, offers important insights: it details how anarchists immediately responded to important issues of their time, and reveals the ways in which the emergence of anarchism was itself a collective effort, emerging from conversation,

debate, and disagreement about how best to create radical change and what that change should look like.

Author Keywords: anarchism, anarchist periodicals, critical discourse analysis, Free Society, Prison Blossoms, The Demonstrator

The Truth and Reconciliation Commission of Canada (TRC) convened in 2008 and focused on the impact of the residential school on Indigenous people in Canada. It was intended to initiate healing in Indigenous communities while contributing to new understandings between Indigenous and non-Indigenous Canadians. In 2015, the TRC's mandate must be completed, and its final task is creating a National Research Centre (NRC) at the University of Manitoba that will hold all of the documentation generated and collected throughout the TRC's tenure. In this thesis I examine many of the challenges the NRC faces, such as lack of funding, institutional oversight, and the enormity of balancing the needs of Indigenous survivors and their communities against building an accessible archive. At a broader level, questions remain about how successful the TRC has been in achieving reconciliation between Indigenous and non-Indigenous Canadians, and how the NRC can work to fulfill this goal.

Author Keywords: archives, Canada, Indigenous, museums, residential schools, truth and reconciliation

My research explores potential motivators for social and health service providers to be more holistic and compassionate with those they serve. From previous research focused on spirituality, I identified seven additional concepts: faith, religion, community, culture, compassion, wellness, and wholeness. Using elements of Appreciative Inquiry, data was collected through a focus group and an in-depth, online survey. The participants work with Indigenous, religious, other spiritually motivated, or non-spiritual social or health service organizations in Peterborough, Ontario, Canada. Prototype concept analysis allowed participants to personally define each concept, and then indicate how much each motivated them. Results indicate, regardless of individual demographics, the definitions and motivations are very personal. The concepts with the most to least motivational impact were community, compassion, spirituality, wellness, wholeness, culture, faith and religion. Participants' voices speak directly through this research. I use their suggestions to make recommendations for improving the systems within which they provide service.

Author Keywords: community, compassion, health services, indigenous knowledge, social services, spirituality

In June 2010, the Group of Twenty (G20) met in Toronto, Ontario. The summit drew large-scale protests that culminated in mass arrests and extensive civil rights violations. Given these outcomes, this thesis examines the security spectacle of the summit to assess the evolving state of public order policing and social movement protest in Canadian law and politics. Connecting the securitization of the summit to the politics of neoliberalism, I argue these overlapping forces helped foment the criminalization of political dissent during the 2010 Toronto G20.

Author Keywords: mega-events, neoliberalism, public order policing, securitization, security, social movements

Decomposition of aquatic macrophytes has an important role in defining lake carbon (C) storage and nutrient dynamics. To test how diversity impacts decomposition dynamics and site-quality effects, I first examined whether the decomposition rate of aquatic macrophytes varies with species richness. Generally, I found neutral effects of mixing, with initial stoichiometry of component species driving decomposition rates. Additionally, external lake conditions can also influence decomposition dynamics. Therefore, I assessed how the decomposition rate of a submersed macrophyte varies across a nutrient gradient in nine lakes. I found decomposition rates varied among lakes. Across all lakes, I found Myriophyllum decomposition rates and changes in stoichiometry to be related to both nutrients and water chemistry. During the incubation changes in detrital stoichiometry were related to lake P and decomposition rates. Aquatic plant community composition and stoichiometry could alter decomposition dynamics in moderately nutrient enriched lakes.

Author Keywords: Aquatic Plants, Decomposition, Diversity, Littoral, Macrophytes, Nutrients