Graduate Theses & Dissertations

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Hydroclimatic and spatial controls on stream nutrient export from forested catchments
Winter nutrient export from forested catchments is extremely variable from year-to-year and across the landscape of south-central Ontario. Understanding the controls on this variability is critical, as what happens during the winter sets up the timing and nature of the spring snowmelt, the major period of export for water and nutrients from seasonally snow-covered forests. Furthermore, winter processes are especially vulnerable to changes in climate, particularly to shifts in precipitation from snow to rain as air temperatures rise. The objective of this thesis was to assess climatic and topographic controls on variability in stream nutrient export from a series of forested catchments in south-central Ontario. The impacts of climate on the timing and magnitude of winter stream nutrient export, with particular focus on the impact of winter rain-on-snow (ROS) events was investigated through a) analysis of long-term hydrological, chemical and meteorological records and b) high frequency chemical and isotopic measurements of stream and snow samples over two winters. The relationship between topography and variability in stream chemistry among catchments was investigated through a) a series of field and laboratory incubations to measure rates and discern controls on nitrogen mineralization and nitrification and b) analysis of high resolution spatial data to assess relationships between topographic metrics and seasonal stream chemistry. Warmer winters with more ROS events were shown to shift the bulk of nitrate (NO3-N) export earlier in the winter at the expense of spring export; this pattern was not observed in other nutrients [i.e. dissolved organic carbon (DOC), total phosphorus (TP), sulphate (SO4), calcium (Ca)]. Hydrograph separation revealed the majority of ROS flow came from baseflow, but the NO3-N concentrations in rainfall and melting snow were so high that the majority of NO3-N export was due to these two sources. Other nutrient concentrations did not show such a great separation between sources, and thus event export of these nutrients was not as great. Proportionally, catchments with varying topography responded similarly to ROS events, but the absolute magnitude of export varied substantially, due to differences in baseflow NO3-N concentrations. Field and laboratory incubations revealed differences in rates of net NO3-N production between wetland soils and upland soils, suggesting that topographic differences amongst catchments may be responsible for differences in baseflow NO3-N. Spatial analysis of digital elevation models revealed strong relationships between wetland coverage and DOC and dissolved organic nitrogen (DON) concentrations in all seasons, but relationships between topography and NO3-N were often improved by considering only the area within 50 or 100m of the stream channel. This suggests nutrient cycling processes occurring near the stream channel may exert a stronger control over NO3-N stream outflow chemistry. Overall, topography and climate exert strong controls over spatial and temporal variability in stream chemistry at forested catchments; it is important to consider the interaction of these two factors when predicting the effects of future changes in climate or deposition. Author Keywords: biogeochemistry, forest, nitrate, south-central Ontario, stream chemistry, winter
Robert Bringhurst and Polyphonic Poetry
Robert Bringhurst states that polyphonic art is a faithful, artistic reflection of the multiplicity of the world’s ecosystems. This ecocritical perspective recognizes that human art informs our understandings of the world, and therefore artists have a moral obligation towards that world. In Chapter One I argue that mimesis should be reclaimed as a useful literary category since all art, regardless of intentions, has an effect on both culture and the natural world. In Chapter Two I argue that by reconnecting publishing craft and philosophy, our books can serve to bring us more in tune with the structures of the natural world. I conclude in Chapter Three by asking how a counterpublic consciousness can be cultivated, and how Bringhurst’s mission of transforming culture might be fully realized. Altogether, this view of literature offers an antidote to Western culture’s destructive tendencies towards the natural world. Author Keywords: Bringhurst, ecocriticism, mimesis, poetry, polyphony, typography
Effects of Silver Nanoparticles on Lower Trophic Levels in Aquatic Ecosystems
Due to their effective antibacterial and antifungal properties, silver nanoparticles (AgNPs) have quickly become the most commonly used nanomaterial, with applications in industry, medicine and consumer products. This increased use of AgNPs over the past decade will inevitably result in an elevated release of nanoparticles into the environment, highlighting the importance of assessing the environmental impacts of these nanomaterials on aquatic ecosystems. Although numerous laboratory studies have already reported on the negative effects of AgNPs to freshwater organisms, only a handful of studies have investigated the impacts of environmentally relevant levels of AgNPs on whole communities under natural conditions. This thesis examines the effects of chronic AgNP exposure on natural freshwater littoral microcrustacean, benthic macroinvertebrate and pelagic zooplankton communities. To assess the responses of these communities to AgNPs, I focused on a solely field-based approach, combining a six-week mesocosm study with a three-year whole lake experiment at the IISD – Experimental Lakes Area (Ontario, Canada). Our mesocosm study tested the effects of AgNP concentration (low, medium and high dose), surface coating (citrate- and polyvinylpyrrolidone [PVP]-coated AgNPs), and type of exposure (chronic and pulsed addition) on benthic macroinvertebrates in fine and stony sediments. Relative abundances of metal-tolerant Chironomidae in fine sediments were highest in high dose PVP-AgNP treatments; however, no negative effects of AgNP exposure were seen on biodiversity metrics or overall community structure throughout the study. I observed similar results within the whole lake study that incorporated a long-term addition of low levels of AgNPs to an experimental lake. Mixed-effects models and multivariate methods revealed a decline in all species of the littoral microcrustacean family Chydoridae in the final year of the study within our experimental lake, suggesting that this taxon may be sensitive to AgNP exposure; however, these effects were fairly subtle and were not reflected in the overall composition of littoral communities. No other negative effects of AgNPs were observed on the pelagic zooplankton or benthic macroinvertebrate communities. My results demonstrate that environmentally relevant levels of AgNPs have little impact on natural freshwater microcrustacean and benthic macroinvertebrate communities. Instead, biodiversity metrics and community structure are primarily influenced by seasonal dynamics and nutrient concentrations across both lakes. This thesis highlights the importance of incorporating environmental conditions and the natural variability of communities when examining the potential risks posed by the release of AgNPs into the environment, as simplistic laboratory bioassays may not provide an adequate assessment of the long-term impacts of AgNPs on freshwater systems. Author Keywords: Benthic macroinvertebrates, IISD - Experimental Lakes Area, Littoral microcrustaceans, Silver nanoparticles, Whole lake experiment, Zooplankton
Reconceptualizing Immigration in Canada
This thesis challenges the contemporary framework of immigration in Canada. Despite Canada’s effort to promote cultural diversity and multicultural citizenship, immigration policy in the last decade has moved towards a model of cultural assimilation. The recent Bill—Strengthening Canadian Citizenship Act—devalues non-European cultures and hinders the successful integration for new immigrants. The problem of contemporary immigration in Canada lies in the narrow and exclusive understanding of immigration. That is, the current immigration framework is rooted in Eurocentrism, which draws exclusively from the economic and cultural values of the West. The Eurocentric understanding of migration not only hinders the successful integration for new immigrants, but it also hinders economic growth and weakens the social cohesion of Canada. For this reason, this thesis offers an alternative framework for understanding immigration. I focus on Chinese migration in Canada and take an interdisciplinary and a conceptual approach in order to present an inclusive understanding of Chinese migration. In particular, I apply the idea of "connected histories" to the context of immigration, and I demonstrate that immigration is a complex and interconnected phenomenon which cannot be reduced to the narratives of economics and ‘Canadian values.’ Instead, immigration should be understood as a process of transnational interactions because it not only allows us to understand benefits that transnational interactions would bring to immigrants, their country of origin and Canada, but it also recognizes different values and the agency of immigrants. Author Keywords: Bill C-24, Chinese Canadians, Eurocentrism, Immigration, Multicultrualism, Transnational
effects of Dissolved Organic Matter (DOM) sources on Pb2+, Zn2+ and Cd2+ binding
Metal binding to dissolved organic matter (DOM) determines metal speciation and strongly influences potential toxicity. The understanding of this process, however, is challenged by DOM source variation, which is not always considered by most existing metal speciation models. Source determines the molecular structure of DOM, including metal binding functional groups. This study has experimentally showed that the allochthonous-dominant DOM (i.e. more aromatic and humic) consistently has higher level of Pb binding than the autochthonous-dominant DOM (i.e. more aliphatic and proteinaceous) by more than two orders of magnitude. This source-discrimination, however, is less noticeable for Zn and Cd, although variation still exceeds a factor of four for both metals. The results indicate that metal binding is source-dependent, but the dependency is metal-specific. Accordingly, metal speciation models, such as the Windermere Humic Aqueous Model (WHAM), needs to consider DOM source variations. The WHAM input of active fraction of DOM participating in metal binding (f) is sensitive to DOM source. The commonly-used f = 0.65 substantially overestimated the Pb and Zn binding to autochthonous-dominant DOM, indicating f needs to be adjusted specifically. The optimal f value (fopt) linearly correlates with optical indexes, showing a potential to estimate fopt using simple absorbance and/or fluorescence measurements. Other DOM properties not optically-characterized may be also important to determine fopt, such as thiol, which shows strong affinity to most toxic metals and whose concentrations are appreciably high in natural waters (< 0.1 to 400 nmol L-1). Other analytical techniques rather than Cathodic Stripping Voltammetry (CSV) are required to accurately quantify thiol concentration for DOM with concentration > 1 mg L-1. To better explain the DOM-source effects, the conditional affinity spectrum (CAS) was calculated using a Fully Optimized ContinUous Spectrum (FOCUS) method. This method not only provides satisfactory goodness-of-fit, but also unique CAS solution. The allochthonous-dominant DOM consistently shows higher Pb affinity than autochthonous-dominant DOM. This source-discrimination is not clearly observed for Zn and Cd. Neither the variability of affinity nor capacity can be fully explained by the variability of individual DOM properties, indicating multiple properties may involve simultaneously. Together, the results help improve WHAM prediction of metal speciation, and consequently, benefit geochemical modelling of metal speciation, such as Biotic Ligand Model for predicting metal toxicity. Author Keywords: Dissolved organic matter, Metal binding, Source, Windermere Humic Aqueous Model
Characterization of a Zn(II)2Cys6 transcription factor in Ustilago maydis and its role in pathogenesis
Ustilago maydis (D.C.) Corda is a biotrophic pathogen that secretes effectors to establish and maintain a relationship with its host, Zea mays. In this pathosystem, the molecular function of effectors is well-studied, but the regulation of effector gene expression remains largely unknown. This study characterized Zfp1, a putative U. maydis Zn(II)2Cys6 transcription factor, as a modulator of effector gene expression. The amino acid sequence of Zfp1 indicated the presence of a GAL4-like zinc binuclear cluster as well as a fungal specific transcription factor domain. Nuclear localization was confirmed by tagging Zfp1 with enhanced green fluorescent protein. Deletion of zfp1 resulted in attenuated hyphal growth, reduced infection frequency, an arrest in pathogenic development, and decreased anthocyanin production. This phenotype can be attributed to the altered transcript levels of genes encoding predicted and confirmed U. maydis effectors in the zfp1 deletion strain during pathogenic growth. Complementation of zfp1 deletion strain with tin2, an effector involved in anthocyanin induction, suggested this effector is downstream of Zfp1 and its expression is influenced by this transcription factor during in planta growth. When wild-type zfp1 was ectopically inserted in the zfp1 deletion strain, pathogenesis and virulence were partially restored. This, coupled with zfp1 over-expression strains having a similar phenotype as the deletion strains, suggested Zfp1 may interact with other proteins for full function. These findings show that Zfp1, in conjunction with one or more binding partners, contributes to U. maydis pathogenesis, virulence, and anthocyanin production through the regulation of effector gene expression. Author Keywords: effector, pathogenesis, transcription factor, Ustilago maydis, Zea mays, zinc finger
All I've Found is Pain and Terror
This thesis is concerned with how specific aesthetic elements function in various contemporary texts to distort, obscure, or illuminate the immoral actions and behaviours being represented. This thesis applies the moral status philosophy of Mary Anne Warren, along with the moral philosophy of Emmanuel Lévinas and Zygmunt Bauman. Close reading and critical analysis are supported by Michele Aaron’s theory of spectatorship. The sublime is explored in Dexter (2006) and Batman: The Dark Knight Returns (1986), the uncanny in Battlestar Galactica (2003) and Westworld (2016), and the abject in The Walking Dead (2003) and World War Z (2006). The intentions of this project are to conduct a formal examination of the relationship between audience and text as it is filtered through aesthetic representation and moral frameworks. This thesis argues that aesthetic effects must be understood in connection to morality for active consumers to engage with these texts as sites for ethical consideration. Author Keywords: aesthetic theory, moral status philosophy, Popular fiction, spectatorship, The Walking Dead, Westworld
Emerging Dynamic Social Learning Theory of a Learning Community of Practice
In current knowledge-based economy, knowledge might be viewed as the most valuable organizational resource in sustaining any organization. Organizational knowledge originates from cognitive learning by individuals situated within organizations. In organizational learning, situated learning of knowledge by individuals is shared to create sustainable organizational competency. Yet, there is inadequate research to understand how situated learning operates as a social learning system within Community of Practice (‘CoP’). Through a case study of a multi-level, non-profit CoP in Ontario, Canada, this qualitative explanatory research contributes to the extant literature by building a unique theoretical framework that provides conceptual insights on linkages between organizational knowledge, social learning system, and organizational competency, in sustaining the organizational CoP. Using Straussian grounded theory methodology, qualitative primary data from in-depth interviews, participant observations, and documents were triangulated and analysed abductively to reveal an emerging dynamic knowledge-based social learning theory towards explaining how situated learning sustains this learning CoP. Author Keywords: Community of Practice, Grounded Theory, Organizational Knowledge, Organizational Learning, Organizational Sustainability, Situated Learning
Comparative phylogeography in conservation biology
Phylogeographic histories of taxa around the Great Lakes region in North America are relevant to a range of ongoing issues including conservation management and biological invasions. In this thesis I investigated the comparative phylogeographic histories of plant species with disjunct distributions and plant species with continuous distributions around the Great Lakes region; this is a very dynamic geographic area with relatively recent colonisation histories that have been influenced by a range of factors including postglacial landscape modifications, and more recently, human-mediated dispersion. I first characterized four species that have disjunct populations in the Great Lakes region: (Bartonia paniculata subsp. paniculata, Empetrum nigrum, Sporobolus heterolepis, and Carex richardsonii). Through comparisons of core and disjunct populations, I found that a range of historical processes have resulted in two broad scenarios: in the first scenario, genetically distinct disjunct and core populations diverged prior to the last glacial cycle, and in the second scenario more recent vicariant events have resulted in genetically similar core and disjunct populations. The former scenario has important implications for conservation management. I then characterized the Typha species complex (T. latifolia, T. angustifolia, T. x glauca), which collectively represent species with continuous distributions. Recent microevolutionary processes, including hybridization, introgression, and intercontinental dispersal, obscure the phylogeographic patterns and complicate the evolutionary history of Typha spp. around the Great Lakes region, and have resulted in the growing dominance of non-native lineages. A broader geographical comparison of Typha spp. lineages from around the world identified repeated cryptic dispersal and long-distant movement as important phylogeographic influences. This research has demonstrated that comparisons of regional and global evolutionary histories can provide insight into historical and contemporary processes useful for management decisions in conservation biology and invasive species. Author Keywords: chloroplast DNA, conservation genetics, disjunct populations, invasive species, phylogeography, postglacial recolonisation
On the Cyberflaneur
This thesis is a critical response to Evgeny Morozov’s article proclaiming the death of the cyberflâneur. Suspicious of the superficiality of his argument, I developed a practico-theoretical project to prove that the cyberflâneur is not dead but alive – or, if it were dead, to rescue it from its grave and bring it back to life. In the course of my response to Morozov, I develop a theoretical foundation that allows me to continue thinking about the concept and practice of the cyberflâneur in the context of the Internet. In doing so, I rely on Gilles Deleuze and Felix Guattari’s “Treatise on Nomadology: The War Machine” (2011), in combination with a history of the tradition of wandering. We are living in a postmodern-posthuman era driven by the chaotic and confusing forces that are manifested through the Internet. As such, it is no longer enough to be concerned with opening the space where we live, move and think; we cannot retreat to nature, we can’t escape society. However, I see potential in the Internet. The Internet, as a physical and material network, can be actualized as an apparatus of capture. It operates as a medium for accelerating or limiting speed, or as an apparatus for the control of the transmission of information. I develop the cyberflâneur as an aesthetic figure that reveals the Internet’s potential. If these revelations happen to be transmitted, then everyday life can again become an object of dispute, rather than unmeditated habituation. Author Keywords: Cyberflâneur, Everyday Life, Internet, Nomadology, Research-creation, Wandering
“It's like getting a new car without the manual”
This study explored teacher infusion of Indigenous curriculum content through interviews with ten non-Indigenous teachers of social studies and history. The interviews centered on teacher perceptions of preparedness to implement Ontario’s recent TRC curriculum revisions, which include more about the contributions, histories, cultures, and perspectives of Indigenous peoples. A brief analysis of Ontario’s First Nation, Métis, and Inuit Education Policy Framework is included, alongside critiques of the Eurocentrism at the heart of education systems. The interviews revealed that many of the teachers were committed to Indigenous education and learning more, but they felt unprepared and lacked resources to teach Indigenous curriculum content with confidence. This study highlighted the critical role of settler teachers in Indigenous education and the importance of teachers undertaking settler unsettling in order to be effective and appropriate in Indigenous curriculum delivery. Individual changes must occur alongside educational system decolonization with a particular focus on teacher preparation. Author Keywords: cognitive imperialism, Indigenous Education, Ontario, settler educator, settler unsettling, TRC curriculum
An Analysis of Hafted Biface Variability in the Kawartha Lakes and Trent River Drainage Region
The objective of this thesis is to evaluate the temporal sensitivity of morphological variability in hafted bifaces in the Kawartha Lakes and Trent River drainage region. This provides a base of information that will enable future analyses that address the possible sources of this variability and to test the robustness of existing typological categories of hafted bifaces for relative dating. This base of information is established via the use of a principal component analysis of shape, raw material, and use-life data from a large sample of hafted bifaces in the region, using a new geometric morphometrics method designed to improve the accuracy of shape representation. The results of the analysis indicate that while certain typological categories may represent distinct morphotypes that are temporally sensitive, the majority of typological categories in the sample show high, overlapping morphological variability that cannot be confidently correlated temporally based on shape alone. Author Keywords: Geometric Morphometrics, Morphological Variability, Ontario Archaeology, Principal Component Analysis, Project Point Morphology, Projectile Point Typology

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Graduate student theses produced at Trent University. You may also browse theses and dissertations by year, program, or author.

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