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Graduate Theses & Dissertations
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- Monitoring and fate of selected tire-derived organic contaminants
- Road runoff is a vector for the transport of potentially toxic chemicals into receiving waters. In this study, selected tire-derived chemicals were monitored in surface waters of rivers adjacent to two high traffic highways in the Greater Toronto Area in Ontario, Canada. Composite samples were collected from the Don River and Highland Creek in the GTA during 5 hydrological events that occurred in the period between early October 2019 and late March 2020, as well as an event in August 2020. Grab samples were collected from these rivers during a period of low flow in August 2020, as well as during a storm event in July of 2020. Analysis was performed using ultra-high pressure liquid chromatography with high resolution mass spectrometric detection (UHPLC-HRMS). Hexamethoxymethylmelamine (HMMM), a cross-linker of tire material, was detected at elevated concentrations (> 1 µg/L) during rain events in the fall and winter of 2019-20 and during a period of rapid snow melt in early March of 2020. These samples were also analyzed for the tire additive, 6PPD, and its oxidation by-product, 6PPD-quinone, as well as 1,3-diphenylguanidine (DPG). In many samples collected from the Don River and Highland Creek during storm events, the estimated concentrations of 6PPD-quinone exceeded the reported LC50 of 0.8 µg/L for Coho salmon exposed to this compound. Temporal samples collected at 3-hour intervals throughout rain event the October 2020 showed that there was a delay of several hours after the start of the event before these compounds reached their peak concentrations. In addition, 26 candidate transformation products and precursor compounds of HMMM were monitored; 15 of these compounds were detected in surface waters in the GTA. The maximum total concentration of this class of methoxymethylmelamine compounds in surface water samples was estimated to be 18 µg/L. There is limited knowledge about the properties of HMMM, its precursor contaminants, and its transformation compounds, as well as their fate in the environment. COSMO-RS solvation theory was used to estimate the physico-chemical properties of HMMM and its derivatives. Using the estimated values for these properties (e.g., solubility, vapour pressure, log Kow) as inputs to the Equilibrium Criterion (EQC) fugacity-based multimedia model, the compounds were predicted to readily partition into aqueous media, with mobility in water increasing with the extent of loss of methoxymethyl groups from HMMM. Overall, this study contributes to the growing literature indicating that potentially toxic tire-wear compounds are transported via road runoff into urban surface waters. In addition, this study provides insight into the environmental behaviour of HMMM and its transformation products. Author Keywords: 6PPD-quinone, COSMOtherm, Fugacity, Hexamethoxymethylmelamine, Road runoff, Tire wear
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- Educational Data Mining and Modelling on Trent University Students’ Academic Performance
- Higher education is important. It enhances both individual and social welfare by improving productivity, life satisfaction, and health outcomes, and by reducing rates of crime. Universities play a critical role in providing that education. Because academic institutions face resource constraints, it is thus important that they deploy resources in support of student success in the most efficient ways possible. To inform that efficient deployment, this research analyzes institutional data reflecting undergraduate student performance to identify predictors of student success measured by GPA, rates of credit accumulation, and graduation rates. Using methods of cluster analysis and machine learning, the analysis yields predictions for the probabilities of individual success. Author Keywords: Educational data mining, Students’ academic performance modelling
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- Legacy Effects Associated with the World’s Largest Ongoing Liming and Forest Regeneration Program in Sudbury, Ontario, Canada
- Soil and tree chemistry were measured across 15 limed sites that were established 14 to 37 years ago within the Sudbury barrens in Ontario, along with two unlimed pre-treatment condition reference sites and an unlimed remnant pine forest. Soil pH and base cation (calcium (Ca), magnesium (Mg), and potassium (K)) concentrations were elevated in surface organic [FH] horizons up to 37-years post limestone treatment. Limestone in the organic horizon was evident by higher Ca/Sr ratios (a good marker of dolomite) in younger sites. Base cation mass budgets were generally unable to account for the mass of added Ca and Mg. Sudbury is characterized by widespread metal contamination. Metal (copper (Cu), nickel (Ni), and lead (Pb)) concentrations were generally greatest within the FH horizon and unrelated to stand age. Copper and Ni concentrations in soil generally decreased with distance from the nearest smelter. Metal partitioning (Kd) in soil was most influenced by soil pH rather than organic matter suggesting that as liming effects fade over time metal availability may increase. Author Keywords: Afforestation, Degraded, Limestone, nutrient, Space-for-time, Sudbury
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- Characterizing the demographic history and prion protein gene variation to infer susceptibility to chronic wasting disease in a naïve population of white-tailed deer (Odocoileus virginianus)
- Assessments of the adaptive potential of natural populations are essential for understanding and predicting responses to environmental stressors like climate change and infectious disease. The range of stressors species face in a human-dominated landscape, often have contrasting effects. White-tailed deer (Odocoileus virginianus, deer) are expanding in the northern part of their range following decreasing winter severity and increasing forage availability, caused by climate change. Chronic wasting disease (CWD), a prion disease affecting cervids, is likewise expanding and represents a major threat to deer and other cervids We obtained tissue samples from free-ranging deer across their native range in Ontario, Canada which has yet to detect CWD in wild populations of cervids. High throughput sequencing was used to assess neutral genomic variation and variation in the gene responsible for the protein that misfolds into prions when deer contract CWD, known as the PRNP gene. Neutral variation revealed a high number of rare alleles and no population structure, consistent with an expanding population of deer. Functional genetic variation revealed that the frequencies of variants associated to CWD susceptibility and disease progression were evenly distributed across the landscape and the frequencies were consistent with deer populations not infected with CWD. These findings suggest that an observable shift in PRNP allele frequencies likely coincides with the start of a novel CWD epidemic. Sustained surveillance of genomic and genetic variation can be a useful tool for CWD-free regions where deer are managed for ecological and economic benefits. Author Keywords: Canadian wildlife, population genetics, prion, PRNP, RADseq, ungulate
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- Rendering New Insights
- The Upper Paleolithic sequence at Vale Boi, Portugal, represents an early example of resource intensification, for which evidence of both diet diversification and intensified utilization of faunal remains has been published. The current research project tests the hypothesis that bone grease rendering was occurring throughout the Upper Paleolithic sequence at Vale Boi. As there are various issues of equifinality which makes the identification of bone grease rendering challenging, data from experimental bone grease rendering studies were utilized. The resulting analysis demonstrated limited evidence in support of a sustained use of bone grease rendering during the Upper Paleolithic sequence. However, evidence suggested that alternate bone processing activities and discard behaviours may have been occurring at the site. This suggests that the dietary behaviours of the foragers at Vale Boi were more varied than previously hypothesized. Author Keywords: Archaeozoology, Bone Grease Rendering, Faunal Analysis, Iberia, Resource Intensification, Upper Paleolithic
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- Influence of geodemographic factors on electricity consumption and forecasting models
- The residential sector is a major consumer of electricity, and its demand will rise by 65 percent by the end of 2050. The electricity consumption of a household is determined by various factors, e.g. house size, socio-economic status of the family, size of the family, etc. Previous studies have only identified a limited number of socio-economic and dwelling factors. In this thesis, we study the significance of 826 geodemographic factors on electricity consumption for 4917 homes in the City of London. Geodemographic factors cover a wide array of categories e.g. social, economic, dwelling, family structure, health, education, finance, occupation, and transport. Using Spearman correlation, we have identified 354 factors that are strongly correlated with electricity consumption. We also examine the impact of using geodemographic factors in designing forecasting models. In particular, we develop an encoder-decoder LSTM model which shows improved accuracy with geodemographic factors. We believe that our study will help energy companies design better energy management strategies. Author Keywords: Electricity forecasting, Encoder-decoder model, Geodemographic factors, Socio-economic factors
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- “Has anybody got my back?”
- Drawing on pedagogies of care, queer pedagogy and Foucault’s concept of biopower, this critical narrative study of six women teachers at an Ontario school uses interview data to explore how teaching affects women’s bodies. Findings include the dominance of men in schools; the high rate of violence against teachers committed by students; participants’ unwillingness to show bodily discomfort to students; and the profound effect of motherhood on teaching practice. I call on educators and school administrators to embed care of students’ and teachers’ bodies into the practices of schooling. I also propose that instead of erasing teacher corporeality from classrooms, we allow students to care for teachers’ bodies as part of a healthy, reciprocal caring relationship, developing students’ and sustaining teachers’ capacity to care. Given the underrepresentation of women’s voices speaking about violence against teachers, this thesis is also a repository for women’s narrated stories of assault in Ontario schools. Author Keywords: biopedagogies, body, care, narrative inquiry, pedagogy, teacher
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- Pathways to Innovation
- Research and development activities conducted at universities and firms fuel economic growth and play a key role in the process of innovation. Specifically, prior research has investigated the widespread university-to-firm research development path and concluded that universities are better suited for early stage of research while firms are better positioned for later stages. This thesis aims to present a novel explanation for the pervasive university-to-firm research development path. The model developed uses game theory to visualize and analyze interactions between a firm and university under different strategies. The results reveal that as academic research signals knowledge it helps attract tuition paying students. Generating these tuition revenues is facilitated by university research discoveries, which, once published, a firm can build upon to make new innovative products. In an environment of weak intellectual property rights, moreover, the university-to-firm research development path enables firms to bypass the hefty costs that are involved in basic research activities. The model also provides a range of solution scenarios where a university and firm may find it viable to initiate a research line. Author Keywords: Game theory, Intellectual property rights, Nash equilibrium, Research and development, University to-firm research path
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- Effects of hydrologic seasonality on dissolved organic matter composition, export, and biodegradability in two contrasting streams
- Environmental and seasonal processes are important watershed drivers controlling the amount, composition, and fate of dissolved organic matter (DOM) in aquatic ecosystems. We used ten months of water samples and eight months of bioassay incubations from two contrasting catchments (agriculture and natural, forested) to assess the effects of seasonal variability on the composition, export, and biodegradability of DOM. As expected, the DOM composition and exports were more allochthonous-like and autochthonous-like in the forest and agriculture streams, respectively. However, we found no relationship between DOM composition and biodegradability in our study, suggesting that broad environmental factors play a large part in determining bioavailability of DOM. We found that both differences between the catchments and seasonal variability in hydrology and water temperature cause shifts in DOM composition that can affect exports and potentially affect its susceptibility to microbial activity. More research is needed to fully understand the impact of land use and temporal variability on bioavailability and delivery to downstream ecosystems. Author Keywords: Bioavailable dissolved organic carbon, Biodegradability, Dissolved organic matter, Export, Seasonality, Streams
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- Sinc-Collocation Difference Methods for Solving the Gross-Pitaevskii Equation
- The time-dependent Gross-Pitaevskii Equation, describing the movement of parti- cles in quantum mechanics, may not be solved analytically due to its inherent non- linearity. Hence numerical methods are of importance to approximate the solution. This study develops a discrete scheme in time and space to simulate the solution defined in a finite domain by using the Crank-Nicolson difference method and Sinc Collocation Methods (SCM), respectively. In theory and practice, the time discretiz- ing system decays errors in the second-order of accuracy, and SCMs are decaying errors exponentially. A new SCM with a unique boundary treatment is proposed and compared with the original SCM and other similar numerical techniques in time costs and numerical errors. As a result, the new SCM decays errors faster than the original one. Also, to attain the same accuracy, the new SCM interpolates fewer nodes than the original SCM, which saves computational costs. The new SCM is capable of approximating partial differential equations under different boundary con- ditions, which can be extensively applied in fitting theory. Author Keywords: Crank-Nicolson difference method, Gross-Pitaevskii Equation, Sinc-Collocation methods
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- Olives in the Mountains
- Olives have been grown in the Mediterranean region for millennia and have been a staple crop in many of its cultures. This was never more true than during the Hellenistic (323 – 133 BC) and Roman (133 BC – AD 450) periods in the Mediterranean. This thesis examines the territory of the Roman city of Sagalassos in the region of Pisidia, modern province of Burdur, and determines if olives could have been cultivated in the territory. While there have been studies that state olives were cultivated in the territory during the Hellenistic and Roman periods, modern farmers as well as agronomic manuals state that such growth is not possible. This thesis present data that indicates that olives were grown in the territory of Sagalassos, but also examines the conditions olives require to grow and if such conditions existed in Pisidia. Through this I will be able to conclude whether the past presentation of data has does indeed prove that olives were grown within the territory of Sagalassos. Author Keywords: Agricultural Decision Making, Olives, Pisidia, Roman Agriculture, Sagalassos, Turkey
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- Exploring Characteristics of those Utilizing Different Modalities of Treatment for Substance Use Disorders
- Substance use disorder (SUD) is a pervasive psychological disorder detrimentally impacting both individuals and society on a psychological, economic, and social level. The best protocol for treating SUD as well as what defines success in treatment is often debated in the research. However, researchers agree that different psychosocial factors can influence outcomes. The literature suggests that mood, dark personality traits (narcissism and psychopathy), social supports, and state of change may be associated with treatment for SUD. The current study explored whether these factors predicted the type of treatment (abstinence-based or harm reduction) individuals with SUD were in. The sample consisted of 37 participants in a 12-step abstinence-based program and 65 in a harm reduction program at a local hospital. Results indicated that those in abstinence-based groups reported significantly fewer symptoms of anxiety and depression, lower levels of narcissism and psychopathy, more social supports, and advanced stage of change in comparison to those attending a harm reduction program. In addition, depression, narcissism, and perceived social support were significant predictors of treatment group membership. These findings suggest that those involved in abstinence-based groups appear to experience overall more wellness than those in harm reduction. Although further research is needed to specify the relations among factors, this study is a step towards understanding the difference between people who utilize one program versus another. Author Keywords: Abstinence, Addiction, Harm Reduction, Personality, Treatment