Graduate Theses & Dissertations

Pages

Size and fluorescence properties of allochthonous dissolved organic matter
Dissolved organic matter (DOM) is a mixture of molecules with dynamic structure and composition that are ubiquitous in aquatic systems. DOM has several important functions in both natural and engineered systems, such as supporting microorganisms, governing the toxicity of metals and other pollutants, and controlling the fate of dissolved carbon. The structure and composition of DOM determine its reactivity, and hence its effectiveness in these ecosystem functions. While the structure, composition, and reactivity of riverine and marine DOM have been previously investigated, those of allochthonous DOM collected prior to exposure to microbes and sunlight have received scant attention. The following dissertation constitutes the first in-depth study of the structure, composition, and reactivity of allochthonous DOM at its point of origin (i.e. leaf leachates, LLDOM), as detected by measuring its size and optical properties. Concomitantly, novel chemometric methods were developed to interpret size-resolved data obtained using asymmetrical flow field-flow fractionation, including spectral deconvolution and the application of machine learning algorithms such as self-organizing maps to fluorescence data using a dataset of more than 1000 fluorescence excitation-emission matrices. The size and fluorescence properties of LLDOM are highly distinct. Indeed, LLDOM was correctly classified as one of 13 species/sources with 92.5% accuracy based on its fluorescence composition, and LLDOM was distinguished from riverine DOM sampled from eight different rivers with 98.3% accuracy. Additionally, both fluorescence and size properties were effective conservative tracers of DOC contribution in pH-controlled mixtures of leaf leachates and riverine DOM over two weeks. However, the structure of LLDOM responded differently to pH changes for leaves/needles from different tree species, and for older needles. Structural changes were non-reversible. Copper-binding strength (log K) differed for the different fluorescent components of DOM in a single allochthonous source by more than an order of magnitude (4.73 compared to 6.11). Biotransformation preferentially removed protein/polyphenol-like fluorescence and altered copper-binding parameters: log K increased from 4.7 to 5.5 for one fluorescent component measured by fluorescence quenching, but decreased from 7.2 to 5.8 for the overall DOM, as measured using voltammetry. The complexing capacity of DOM increased in response to biotransformation for both fluorescent and total DOM. The relationship between fluorescence and size properties was consistent for fresh allochthonous DOM, but differed in aged material. Since the size and fluorescence properties of LLDOM are strikingly different from those of riverine DOM, deeper investigation into transformative pathways and mixing processes is required to elucidate the contribution of riparian plant species to DOM signatures in rivers. Author Keywords: Analytical chemistry, Chemometrics, Dissolved organic matter (DOM), Field-flow fractionation, Fluorescence spectroscopy, Parallel factor analysis (PARAFAC)
Effects of Hydroelectric Corridors on the Distribution of Female Caribou (Rangifer tarandus) on the Island of Newfoundland
A species of concern is caribou (Rangifer tarandus), a species in decline across most of the circumpolar North, including the island of Newfoundland. Resource exploitation across caribou ranges is projected to accelerate in the coming decades as oil extraction, roads, forest harvesting, and mining encroach upon their habitat. Hydroelectric corridors, in particular, are anticipated to expand significantly. The effects of these linear developments on caribou habitat remain unclear. I capitalized on an existing dataset of nearly 700 radio‐tracked female caribou, 1980‐2011, to determine the long‐term effects of hydroelectric corridors on their seasonal distributions. Using an island-wide landcover map, I tested for preference or avoidance hydroelectric corridors in each of 4 seasons using the Euclidean Distance habitat selection technique at the extent of the population ranges (broad scale) for each decade (1980s, 1990s, 2000s). I also examined the distribution of caribou ≤10 km and ≤20 km from corridors (narrow scale) for five herds. At the broad scale, the response was highly variable. Female caribou were most likely to avoid corridors during the 1980s, but they often exhibited little aversion, even preference for corridors, particularly in the 1990s and 2000s. Hydroelectric corridors, therefore, did not appear to be limiting at this scale. I surmise that these long-term shifts reflect the heightened density-dependent food limitation for Newfoundland caribou. At the narrow scale, avoidance of corridors was common – typically, a 50% reduction in use within 2-5 km of the corridor. Consistent with the broad scale, caribou exhibited the strongest tendency for avoidance in the 1980s compared to subsequent decades. Understanding space-use remains central to the study of caribou ecology. Hydroelectric lines in Newfoundland tended to coincide with other anthropogenic features. Cumulative effects must be considered to understand the full range of effects by human developments on caribou. Author Keywords: Caribou, distribution, habitat, hydroelectric, Newfoundland, Rangifer tarandus
Sex-Specific Graphs
Sex-specific genetic structure is a commonly observed pattern among vertebrate species. Facing differential selective pressures, individuals may adopt sex-specific life historical traits that ultimately shape genetic variation among populations. Although differential dispersal dynamics are commonly detected in the literature, few studies have investigated the potential effect of sex-specific functional connectivity on genetic structure. The recent uses of Graph Theory in landscape genetics have demonstrated network capacities to describe complex system behaviors where network topology intuitively represents genetic interaction among sub-units. By implementing a sex-specific network approach, our results suggest that Sex-Specific Graphs (SSG) are sensitive to differential male and female dispersal dynamics of a fisher (Martes pennanti) metapopulation in southern Ontario. Our analyses based on SSG topologies supported the hypothesis of male-biased dispersal. Furthermore, we demonstrated that the effect of the landscape, identified at the population-level, could be partitioned among sex-specific strata. We found that female connectivity was negatively affected by snow depth, while being neutral for males. Our findings underlined the potential of conducting sex-specific analysis by identifying landscape elements that promotes or impedes functional connectivity of wildlife populations, which sometimes remains cryptic when studied at the population level. We propose that SSG approach would be applicable to other vagile species where differential sex-specific processes are expected to occur. Author Keywords: genetic structure, Landscape Genetics, Martes pennanti, Population Graph, sex-biased dispersal, Sex-Specific Graphs
Why not give up? A study on the role of resourcefulness in goal pursuit
Past research suggests that taking a process oriented approach, setting clear and concrete goals, and using both conscious planning and proactive coping are the best methods to be successful with goal pursuit. Also the literature has found that individuals scoring higher in general resourcefulness tend to be more successful at achieving goals than their less resourceful counterparts. My thesis looked at these goal pursuit behaviours under the lens of resourcefulness using a mixed methods approach. After completing Rosenbaum’s self-control scale (1980) assessing general resourcefulness, participants took part in a semi-structured interview asking them about a recent goal they had set and how they dealt with interfering obstacles. The hope was hearing differences about how highly and less resourceful people discuss their goals and setbacks would give a deeper understanding about the characteristics of success. The themes emerging from the interviews were: blame and excuses versus understanding and growth, internal versus external factors, living in the moment versus conscious planning and magical versus realistic thinking. In contrast to low-scoring participants, highly resourceful individuals grew from their setbacks, were internally driven, consciously planned, and thought realistically about their goals. Less resourceful individual, on the other hand blamed outside factors and made excuses, were only motivated externally, didn’t plan out their goals and believed their goals would just magically materialize over time. My discussion focuses on the ability to train lower resourceful individuals over longer interventions, and the applications of understanding and using resourcefulness as a lens in future studies. Author Keywords: Goal, Habits, Quitting, Resourcefulness, Self-Control, Success
Bio-based Polymers from Epoxidized Vegetable Oils Modified by Metathesis
The epoxides of oligomeric self-metathesized soybean oil (MSBO) and cross-metathesized palm oil (PMTAG) and canola oil (CMTAG) containing terminal double bonds were used to produce nonisocyanate polyurethanes (NIPUs) as well as anhydride, amine and thiol-cured epoxies. The synthesized NIPUs displayed metal adhesive properties for CMTAG and MSBO with MSBO being favoured probably due to its plasticizing nature as opposed to CMTAG. The relationship was reversed for the anhydride curing reaction where it was found that CMTAG, due to its lower degree of plasticizing content from the reduced dangling chains, produced higher tensile strengths than MSBO. Both MSBO and CMTAG led to fully cured amine and thiol products that were sticky gels, which prevented physical analyzses of their expected solidified products. PMTAG, due to its low number of reactive groups, was not suitable for the synthesis of these polymers. Author Keywords: Amine-cured epoxy, Anhydride-cured epoxy, Metathesis, Nonisocyanate Polyurethanes, Thiol-cured epoxy
An Evaluation of Wastewater Treatment by Ozonation for Reductions in Micropollutant Toxicity to Fish
Micropollutants are discharged into the aquatic environment with industrial and domestic wastewater and these compounds may cause toxic effects in aquatic organisms. In this study, the toxic effects to fish of micropollutants extracted from ozonated and nonozonated municipal wastewater effluent (MWWE) were measured in order to assess the effectiveness of ozonation in reducing toxicity. Juvenile rainbow trout (Oncorhynchus mykiss) injected with extracts prepared from ozonated MWWE had significantly reduced induction of plasma vitellogenin (VTG), significantly reduced hepatic total glutathione (tGSH) levels and an elevated oxidized-to-total glutathione (GSSG-to-tGSH) ratio. Exposure of Japanese medaka (Oryzias latipes) embryos to extracts prepared from both ozonated and non-ozonated MWWE resulted in elevated developmental toxicity in both treatment groups. These results indicate that wastewater treatment by ozonation reduces the estrogenicity of wastewater, but treatment may induce oxidative stress and embryonic developmental toxicity due to the production of toxic by-products. Author Keywords: Estrogenicity, Micropollutants, Oxidative stress, Ozonation, Toxic by-products, Wastewater
Sacred Space, Ancestors, and Authority
The Middle Formative Period (1000 – 400 B.C.) has increasing become recognized as a critical locus in the development of Lowland Maya socio-political complexity. This period witnessed the founding of numerous ceremonial centers, substantial material cultural innovation, and the advent of mortuary practices indicating developing social differentiation. Recent excavations at the site of Ka’Kabish in Northern Belize have uncovered evidence significantly strengthening this view. Excavations underlying Plaza D-South at Ka’Kabish have revealed a series of bedrock-hewn pits containing offering caches of thousands of shell beads, forty-seven greenstone objects, and extensive ceramic evidence indicating communal ritual and feasting, which is argued by the author to represent a cosmographic diorama of the cave-riddled Underworld. Significantly, this elaborate cosmographic offering event appears to center on the secondary, bundled bedrock-cist burial of an important personage and/or ancestor who is accompanied by a number of finely crafted jade ornaments representing motifs and forms that have previously been interpreted as symbols of authority, rulership, and divine kingship. Comparable contemporary evidence from Northern Belize and beyond has been interpreted through models foregrounding site-founding, place-making, ancestor veneration, and aggrandizer driven social differentiation. By integrating and contrasting these existing models with new evidence from Ka’Kabish, this thesis argues that the mortuary, caching, and architectural practices evidenced at Middle Formative Ka’Kabish represent a glimpse into the incipience of the ideological complex, the socio-cultural processes, and the material manifestations propagating the development of subsequent Maya socio-political complexity, specifically the institution of divine kingship or ch’uhul ahau. Author Keywords: ancestor veneration, ancient Maya, greenstone cache, Ka’Kabish, Belize, Middle Formative, socio-political complexity
Doing it Right
The cyanidation technique is currently a viable technique for gold recovery that can replace the present amalgamation technique in Guyana. To implement this technique effectively, laboratory scale experiments and at scale runs were conducted to determine the best particle size of the ore, cyanide concentration, and leaching time. In addition, the profitability of cyanidation was compared to the amalgamation technique so as to describe the economic value of cyanidation. Results indicated that up to 94% of gold can be recovered from the ore using an ore particle size of 150 (105 µm), meshes, a cyanide concentration of 0.05% and leaching for 24 h. An economic comparison of this technique with the amalgamation technique indicated that although initial costs are high for the cyanidation technique, profits as high as 83% can be achieved after initializing this method whereas profits would be capped at approximately 25% for the amalgamation technique. Keywords: gold recovery, cyanidation, mercury amalgamation, activated car Author Keywords: activated carbon, cyanidation, gold recovery, mercury amalgamation
Imagining a National Research Centre
The Truth and Reconciliation Commission of Canada (TRC) convened in 2008 and focused on the impact of the residential school on Indigenous people in Canada. It was intended to initiate healing in Indigenous communities while contributing to new understandings between Indigenous and non-Indigenous Canadians. In 2015, the TRC's mandate must be completed, and its final task is creating a National Research Centre (NRC) at the University of Manitoba that will hold all of the documentation generated and collected throughout the TRC's tenure. In this thesis I examine many of the challenges the NRC faces, such as lack of funding, institutional oversight, and the enormity of balancing the needs of Indigenous survivors and their communities against building an accessible archive. At a broader level, questions remain about how successful the TRC has been in achieving reconciliation between Indigenous and non-Indigenous Canadians, and how the NRC can work to fulfill this goal. Author Keywords: archives, Canada, Indigenous, museums, residential schools, truth and reconciliation
Spirituality, Community and Compassion Matter! Exploring Motivators to Providing Holistic Social and Health Services in Peterborough, Ontario
My research explores potential motivators for social and health service providers to be more holistic and compassionate with those they serve. From previous research focused on spirituality, I identified seven additional concepts: faith, religion, community, culture, compassion, wellness, and wholeness. Using elements of Appreciative Inquiry, data was collected through a focus group and an in-depth, online survey. The participants work with Indigenous, religious, other spiritually motivated, or non-spiritual social or health service organizations in Peterborough, Ontario, Canada. Prototype concept analysis allowed participants to personally define each concept, and then indicate how much each motivated them. Results indicate, regardless of individual demographics, the definitions and motivations are very personal. The concepts with the most to least motivational impact were community, compassion, spirituality, wellness, wholeness, culture, faith and religion. Participants' voices speak directly through this research. I use their suggestions to make recommendations for improving the systems within which they provide service. Author Keywords: community, compassion, health services, indigenous knowledge, social services, spirituality
Dissent Denied
In June 2010, the Group of Twenty (G20) met in Toronto, Ontario. The summit drew large-scale protests that culminated in mass arrests and extensive civil rights violations. Given these outcomes, this thesis examines the security spectacle of the summit to assess the evolving state of public order policing and social movement protest in Canadian law and politics. Connecting the securitization of the summit to the politics of neoliberalism, I argue these overlapping forces helped foment the criminalization of political dissent during the 2010 Toronto G20. Author Keywords: mega-events, neoliberalism, public order policing, securitization, security, social movements
Regional Assessment of Soil Calcium Weathering Rates and the Factors that Influence Lake Calcium in the Muskoka River Catchment, Central Ontario
(MRC) in central Ontario was carried out to determine the range and spatial distribution of soil Ca weathering rates, and investigate the relationships between lake Ca and soil and catchment attributes. The MRC is acid-sensitive, and has a long history of impacts from industrial emission sources in Ontario and the United States. Small headwater catchments were sampled for soil and landscape attributes (e.g. elevation, slope, catchment area) at 84 sites. Soil Ca weathering rates, estimated with the PROFILE model, were low throughout the region (average: 188 eq/(ha·yr)) compared to global averages, and lower than Ca deposition (average: 292 eq/(ha·yr)). Multiple linear regression models of lake Ca (n= 306) were dominated by landscape variables such as elevation, which suggests that on a regional scale, landscape variables are better predictors of lake Ca than catchment soil variables. Author Keywords: Calcium, Lakes, Regional assessment, Regression, Soils, Weathering

Pages

Description

Graduate student theses produced at Trent University. You may also browse theses and dissertations by year, program, or author.

In collections

Search Our Digital Collections

Query

Enabled Filters

  • (-) ≠ Campbell
  • (-) ≠ Educational Studies

Filter Results

Date

1974 - 2024
(decades)
Specify date range: Show
Format: 2024/05/14

Collection

Author Name

Show more

Name (Any)

Show more

Degree

Degree Discipline

Show more

Subject (Topic)

Show more