Graduate Theses & Dissertations

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Identification and Quantification of Organic Selenium Species Produced by Microbiological Activity in Freshwater Environments
Despite being an essential nutrient at trace levels, selenium can be devastating to aquatic environments when present in excess. There is no apparent correlation between total aqueous selenium concentrations and observed toxic effects because bioaccumulation varies over several orders of magnitude depending on the chemical species of selenium and the biological species present in the lowest trophic level of the aquatic food chain. Despite being used in toxicity models due to its high bioavailability, free selenomethionine had not been found previously in the environment outside of a biological entity. Here, it is confirmed that selenomethionine is produced during the biological treatment of selenium-contaminated wastewater, and released in the effluent along with other discrete organic selenium species, including selenomethionine oxide. This identification followed the development of a rigorous preconcentration and cleanup procedure, allowing for the analysis of these organic selenium species in high-ionic strength matrices. A newly optimized anion-exchange chromatographic separation was coupled to inductively-coupled plasma mass spectrometry for the simultaneous quantification of these organic selenium species along with the more ubiquitous selenium oxyanions, selenite and selenate. This separation method was also coupled to electrospray tandem mass spectrometry for structural confirmation of selenomethionine and selenomethionine oxide. High resolution orbitrap mass spectrometry was used to identify another oxidation product of selenomethionine – a cyclic species which was tentatively identified, by coelution, in a selenium-contaminated river water sample. The production and release of selenomethionine, selenomethionine oxide, Se-(methyl) selenocysteine, and methyl selenic acid were observed for various laboratory algal cultures. Once the presence of free selenomethionine in a water system was confirmed, factors affecting its uptake into algal cultures were examined. The uptake of selenomethionine into Scenedesmus obliquus was noted to be significantly higher under low nitrate conditions, where it was incorporated into selenium-containing proteins more readily than at higher nitrate conditions where other metabolites were produced. With the increasing popularity of biological treatment systems for the remediation of selenium-contaminated waters, these observations, combined with existing knowledge, could be used to make predictions regarding the potential toxicity of selenium in various environmental scenarios. Author Keywords: bioremediation, electrospray mass spectrometry, inductively-coupled plasma mass spectrometry, selenium, selenoamino acids, selenomethionine
Life in the Woods
The North American conservation movement and modern conservation model was created in part because of the exploitative commercial hunting industry that caused the collapse of species such as the bison and auk in the late 19th and early 20th centuries. These historical actions continue to shape views today and the public perception of hunting can often be negative. This thesis engaged with this question of social acceptability by conducting action research to determine hunters’ motivations and how these might affect the way hunting is perceived. As part of this action research, I conducted nine in-depth interviews, a survey of 177 hunters, and a focus group to determine what the dominant motivations were for the hunters studied. I then suggest how the motivations discovered through the focus group, interviews, and survey can work towards the current and future social, economic, cultural, and environmental sustainability of hunting in Ontario. Author Keywords: Ethics, Hunting, Motivations, Ontario, Social Acceptance, Sustainability
Building wind energy landscapes
This thesis project explores landowner experiences of wind energy development through an inductive qualitative case study in Huron County, Ontario. The research included in-depth interviews with landowners focused on landscape and community change, participant observation of Environmental Review Tribunals (ERT), the gathering of participant photos, as well as relevant government and industry documents and media reports. The iterative data gathering and analysis were supported by my observations and reflections while living in affected communities and talking to participants. The study demonstrates how the health debate over wind can inform divisions between neighbours, that local politics have been given a token role as a place for resistance to wind energy development that fails to meaningfully influence projects, and that appeals are legalistic and do not provide an outlet, or place for appellants to be heard. Furthermore, the felt experience of tight knit and fragile communities were disrupted through land leases, as well as changes to the landscape. These disruptions impacted connections to, and associations with place, and are shown to have had negative emotional and physical impacts on some individuals. Supporters of wind development tied their mostly positive views of landscape change to a sense of disruption generally throughout the community. Insights from the research lead to a set of suggested actions that might improve the current situation at the levels of provincial policy, planning, local governance and industry practice. Keywords: wind energy policy, planning, landscape, Ontario, rural communities Author Keywords: Affect, landscape, Ontario, planning, Rural communities, Wind energy policy
Genetic diversity and differentiation of Ontario’s recolonizing fishers (Pekania pennanti)
Fishers (Pekania pennanti) were extirpated from many parts of Ontario in the early 20th century, but as of the early 2000s the species had recolonized most of its historical range. While the primary population genetic structure of fishers in central and eastern Ontario has not changed drastically over the past ten years, we did find evidence of increased secondary structure and a reduction in northward movement from southeastern Ontario, a site of recent immigration from the Adirondacks in northern New York. This may be indicative of a reduction in density and thus in density-dependent migration, or it may be a consequence of the population reaching equilibrium following a period of rapid expansion associated with recolonization. We also observed no variation within central and eastern Ontario at 14 of 15 candidate functional loci we screened, suggesting possible directional or stabilizing selection and a lack of adaptive potential. Author Keywords: fisher, functional genes, Ontario, Pekania pennanti, population genetics, recolonization
Model for the Differential Susceptibility of Strontium Titanate
The appearance of a two-dimensional electron gas (2DEG) in oxide interfaces between strontium titanate (STO) and other materials has become a major area of study. The behaviour of the 2DEG in STO is not well understood in part because the dielectric properties of STO are not well characterized. The differential susceptibility has a major impact on the electric fields within strontium titanate, and therefore to understand the 2DEG a better understanding of the susceptibility is needed. An expression for the soft mode phonon frequency of bulk strontium titanate is derived and used to model the susceptibility as a function of spatially homogeneous electric field, temperature and wavevector. This model is used to discuss the effect of spatially inhomogeneous electric fields and the local vs. nonlocal nature of the susceptibility. The critical exponents and the free energy are determined and discussed. Author Keywords: critical exponents, differential susceptibility, quantum paraelectric, strontium titanate
Social Communicative Factors as Predictors of Symptom Severity in Autism Spectrum Disorders
Early diagnosis of autism spectrum disorder (ASD), while providing many benefits, presents challenges to clinicians such as predicting the stability of symptoms. Accurately predicting symptom severity allows clinicians to confidently diagnose and assign the most appropriate treatment. Little research exists to date to predict symptom severity in children with ASD who have not been exposed to treatment. The present file review examined prelinguistic skills as predictors of symptom severity in a group of young children (age: 18 – 64 months) with ASD (n = 199) who had not been exposed to significant levels of treatment. Hierarchical regression analyses demonstrated that of the two core diagnostic features (social communicative deficits and restricted repetitive behaviours), social communicative skills best predicted symptom severity. Furthermore, social communicative gestures predicted symptom severity after age, adaptive behaviour, restricted repetitive behaviours, and functional gestures had been accounted for. Author Keywords: autism, gestures, predictors, prelinguistic, social communicative, symptom severity
Cognitive and Affective Theory of Mind in Children and Young Adolescents
Recently, a distinction has been made between cognitive theory of mind, the ability to make inferences about other's beliefs and thoughts, and affective theory of mind, the ability to make inferences about other's emotional states. The purpose of this study is to determine if the distinction between cognitive and affective theory of mind is developmentally appropriate and whether the relation between language and theory of mind is maintained when cognitive and affective theory of mind are examined separately. The sample consisted of 20 children aged 6 to 9 years, and 27 children aged 11 to 15 years. Results showed that the older group outperformed the younger group on both cognitive and affective theory of mind, and that different aspects of language were related to each type of theory of mind. This suggests the distinction between cognitive and affective theory of mind may in fact be valid in this age range. Author Keywords: Affective Theory of Mind, Cognitive Theory of Mind, Development, Language
Role of Consumption in Canada’s Economic Sustainability
This thesis addresses the interconnectedness of environmental sustainability and economic sustainability. There is evidence from the Canadian experience that market economies are extremely dependent upon consumption - the most significant factor in determining the overall level of economic activity and economic growth. Therefore, from this perspective, several periods of declining consumption would create a ‘vicious cycle’ [Kaldor, 1967] of economic decline that would be politically unsustainable. The analysis here shows that income inequality drives changes in debt-fueled consumption, and consequently, debt influences consumption. The role of income inequality as a mediating channel of sustainability via the borrowing/lending model presents evidence that ‘conventional’ debt servicing behaviour in the macro-economy can support steady-state economic growth that is, in economic terms, sustainable. Solving the conflict between the environment and the economy lies in private and public investments in new technologies and, most importantly, new social institutions that facilitate economic, political, and environmental, sustainability. Author Keywords: Consumption, Economic Growth, Household Debt, Income Inequality, Sustainability
Colonialism, Capitalism, and the Rise of State Schooling in British Columbia, 1849-1900
This dissertation examines the historical relationship between settler colonialism, capitalism, and the rise of state schooling in what is now known as British Columbia between 1849 and 1900. It aims to “unsettle” conventional views of Canadian schooling history by bringing accounts of Indigenous and non-Indigenous education into one analytical frame, and it shows how the state used different forms of schooling for both Indigenous and non-Indigenous children—company, common, public, mission, day, boarding, and industrial schools—to assist colonial-capitalist social formation in the Pacific Northwest. In combining interdisciplinary insights from Indigenous studies, historical materialism, political economy, and critical pedagogy, the dissertation highlights the ways in which state-supported schooling facilitated capitalist accumulation by colonial dispossession. The central argument of the dissertation is that between 1849 and 1900, colonial, provincial, and federal governments strategically took on greater responsibility for schooling as a way of legitimizing the state and supporting the emergence of a capitalist settler society. Author Keywords: Capitalism, Education, Indian Residential Schools, Indigenous Peoples, Settler Colonialism, Violence
Underdevelopment in Eastern Bechuanaland
This thesis offers a comprehensive look at the changing roles of a colonial built railway in what is now eastern Botswana. It was built for the extraction of mineral wealth and migration of cheap African labour in Southern Africa but it later assumed a different role of shaping the modern Botswana state. The thesis deals with several other issues related to the railway in Bechuanaland including land alienation, the colonial disregard of the chiefs’ authority, racial discrimination and the economic underdevelopment of Bechuanaland. Since there were no other significant colonial developments at the time of independence, this thesis argues that the railway was the only important feature of the British colonisation of Bechuanaland. From early on, the railway attracted different cultures, identities and religions. It was also instrumental in the introduction of an indigenous capitalist class into Bechuanaland. Author Keywords: Bechuanaland, Botswana, colonisation, migration, railway, underdevelopment
Hiya 'aa ma pichas 'ope ma hammako he ma pap'oyyisko (Let Us Understand Again our Grandmothers and our Grandfathers)
The Tamalko (Coast Miwok) North Central California Indigenous people have lived in their homelands since their beginnings. California Indigenous people have suffered violent and uncompromising colonial assaults since European contact began in the 16th century. However, many contemporary Indigenous Californians are thriving today as they reclaim their Native American sovereign rights, cultural renewal, and well-being. Culture Bearers are working diligently as advocates and teachers to re-cultivate Indigenous consciousness and knowledge systems. The Tamalko author offers Indigenous perspectives for hinak towis hennak (to make a good a life) through an ethno-autobiographical account based on narratives by Culture Bearers from four Indigenous North Central California Penutian-speaking communities and the author’s personal experiences. A Tamalko view of finding and speaking truth hinti wuskin ʼona (what the heart says) has been the foundational principle of the research method used to illuminate and illustrate Indigenous North Central California consciousness. Author Keywords: Consciousness, Culture Bearers, Indigenous, North Central California, Penutian, re-cultivation
Technology of Consent
The 1980s in the United States have come into focus as years of extensive ideological and socioeconomic fracture. A conservative movement arose to counter the progressive gains of previous decades, neoliberalism became the nation’s economic mantra, and détente was jettisoned in favour of military build-up. Such developments materialized out of a multitude of conflicts, a cultural crisis of ideas, perspectives, and words competing to maintain or rework the nation’s core structures. In this dissertation I argue that alongside these conflicts, a crisis over technology and its ramifications played a crucial role as well, with the American public grasping for ways to comprehend a nascent technoculture. Borrowing from Andrew Feenberg, I define three broad categories of popular conceptualization used to comprehend a decade of mass technical and social transformations: the instrumental view, construing technology as a range of efficient tools; the substantive view, insisting technology is an environment that determines its subjects; and a critical approach, which recognizes the capacity for technology to shape subjects, but also its potential to aid new social agendas. Using Feenberg’s categories as interpretive lenses, I foreground these epistemologies in three of the decade’s most popular formations of literary science fiction (sf), and describe the broader discourses they participated in: military sf is connected to military strategy and weapons development (instrumental), cyberpunk to postmodernism and posthumanism (substantive), and feminist sf to feminist theory and politics (critical). These were not just discursive trajectories, I claim, but vital contributors to the material construction of what Antonio Gramsci would call hegemonic and counterhegemonic formations. While the instrumental paradigm was part of the decade’s prevailing hegemonic make-up, substantive and critical discourses offered an alternative to the reality of cowboy militarism and unchecked technological expansion. By engaging with the decade’s texts—from There Will Be War to RoboCop to “A Cyborg Manifesto”—I hope to illuminate what I call the technology of consent, the significance of technological worldviews for modern technocultures, where such views are consented to by subaltern groups, and at the same time the existence of consent itself as a kind of complex social technology in the first place. Author Keywords: American History, Discourse, Hegemony, Science Fiction, Technoculture, Technology

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Format: 2024/03/28