Graduate Theses & Dissertations

Bio-based Polymers from Epoxidized Vegetable Oils Modified by Metathesis
The epoxides of oligomeric self-metathesized soybean oil (MSBO) and cross-metathesized palm oil (PMTAG) and canola oil (CMTAG) containing terminal double bonds were used to produce nonisocyanate polyurethanes (NIPUs) as well as anhydride, amine and thiol-cured epoxies. The synthesized NIPUs displayed metal adhesive properties for CMTAG and MSBO with MSBO being favoured probably due to its plasticizing nature as opposed to CMTAG. The relationship was reversed for the anhydride curing reaction where it was found that CMTAG, due to its lower degree of plasticizing content from the reduced dangling chains, produced higher tensile strengths than MSBO. Both MSBO and CMTAG led to fully cured amine and thiol products that were sticky gels, which prevented physical analyzses of their expected solidified products. PMTAG, due to its low number of reactive groups, was not suitable for the synthesis of these polymers. Author Keywords: Amine-cured epoxy, Anhydride-cured epoxy, Metathesis, Nonisocyanate Polyurethanes, Thiol-cured epoxy

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